HAM - Handbook of Analytical Methods

ION CHROMATOGRAPHY

HAM - Handbook of Analytical Methods Description of Technique Examples Analytical Information Terms Typical Applications Mee Specification HAM


DESCRIPTION OF TECHNIQUE

Ion Chromatography (IC) is the separation and quantification of anions and cations using Liquid Chromatography (LC). LC is an analytical technique based on the separation of the components of a mixture in solution by selective absorption. There are basically three modes of separation: liquid/liquid, liquid/solid, and molecular size. Once the components have been separated they are measured by a conductivity detector.

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EXAMPLES
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Sample Example
Sample Example
Minimum detection limits for common ions Chromatogram of a 0.02 ppm F, 0.1 ppm CI, NO2, Br, NO3, PO4-2, SO4-2 standard


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ANALYTICAL INFORMATION

Material identification - Comparisons made against known reference materials.

Quantification - Concentrations of components can be determined by establishing a standard curve of known concentrations.

Sensitivity - Detection limits down to parts per billion (ppb) levels.

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TYPICAL APPLICATIONS

  • Determination of ionic species in plating baths
  • Determination of acidic thermal decomposition products of polymer materials
  • Determination of ionic contamination on critical components


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MEE SPECIFICATIONS

Model:Waters 626 SILK Pump & Water 432 Conductivity Detector

Sample must be able to go into solution with a solvent compatible to the LC system, or the components of interest must be able to be extracted from the sample. Components of interest must cause a change in the conductivity of the solute to be detected.

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